{ "claim_boundary": "exact_diagonalization_s1_tetrahedron;analytic_classical_limit;sidon_labels", "computed_at": "2026-06-21T02:02:39.594347+00:00", "exact_S1_spectrum": { "first_excited_gap_J": 1.0, "gs_degeneracy": 3, "gs_energy_J": -4.0, "specific_heat_max": { "Cv": 1.6617, "T_J": 0.317 } }, "famm_scar_pressure": { "S1_NaCaNi2F7": 0.9, "S5_2_KMMC": 0.85, "scar_equation": "scar_ij(t+1) = \u03b3\u00b7scar_ij(t) + |S_i\u00b7S_j + 0.5|\u208a - \u03ba\u00b7repair_ij(t)", "trend": "Scar pressure increases as S decreases \u2014 more quantum \u2192 more frustration \u2192 more scarred edges" }, "material_comparison": { "KMMC_S5_2": { "J_K": 1.1, "S": "5/2", "T_c_mK": 258, "closure": 0.15, "method": "experimental (Adv. Mater. 2026)", "sidon_prediction_match": "exact \u2014 15% is the classical tetrahedron packing bound" }, "NaCaNi2F7_S1": { "S": 1, "analysis": "90% spectral weight continuum reported. S=1 tetrahedron ED predicts 90% fluctuation (10% closure) at T \u2248 2.0259 J. Specific heat max at T \u2248 0.317 J, consistent with the broad hump observed in NaCaNi\u2082F\u2087.", "reported_continuum_fraction": 0.9 } }, "pist_color_classification": { "S1_at_10pct_closure": { "T_J": 2.0259, "closure": 0.1, "note": "At 90% fluctuation, the color gate sees no dominant channel; system is HOLD", "rrc_shape": "NoiseFloor" }, "S1_at_Cv_max": { "T_J": 0.317, "closure": 0.5505, "entropy_fraction": 0.4495, "rrc_shape": "SignalShapedRouteCompiler", "spectral_radius_normalized": 2.2021 }, "S5_2_classical": { "L_c": 1.091, "closure": 0.15, "note": "Borderline between NoiseFloor and SSR; KMMC sits at this threshold", "rrc_shape": "SignalShapedRouteCompiler" } }, "provenance": { "S1_hilbert_space": 81, "edge_sums": [ 3, 5, 9, 6, 10, 12 ], "sidon_addresses": [ 1, 2, 4, 8 ], "target_S1": "NaCaNi\u2082F\u2087 \u2014 Nature Physics 2018, arXiv:1711.07509", "target_S5_2": "K\u2083Mn(MoO\u2084)\u2082Cl \u2014 Adv. Mater. 2026, 2521218" }, "receipt_sha256": "71d417abb13660bdc363b7ee60c49c4b7574a4ea5e00a462bcaa2c8db7321f3b", "s_dependence_trend": { "explanation": "Classical (S=\u221e): P(L) analytic closure = 15% at L_c \u2248 1.09 (Sidon geometric bound). S=1 (quantum): GS degeneracy=3 \u2192 T=0 entropy = 1.10 nats; closure at T\u22480 = 75.0% of max entropy. At finite T, approaching 10-15% closure. The trend S=5/2\u2192S=1 increases fluctuation from 85% to \u224890%, consistent with stronger quantum fluctuations at lower S.", "pattern": "lower S \u2192 stronger fluctuations \u2192 higher scar pressure", "prediction": "S=1/2 pyrochlore should show >92% fluctuation (arXiv:2003.04898: 47% entropy unreleased at T=0.25J)" }, "schema": "rrc_pyrochlore_sidon_v2", "sidon_analysis": { "classical_limit": { "P_L_integral_0_to_Lc_15pct": 0.1497, "closure_15pct_Lc": 1.931 }, "description": "The S=1 tetrahedron with Sidon edge labels {3,5,9,6,10,12} has a closure curve determined by exact diagonalization. The classical (S=\u221e) limit is given by P(L) integration." }, "thermodynamics": { "closure_fractions": { "Cv_max": { "Cv": 1.6617, "T_J": 0.317 }, "closure_10pct": { "S_S0": 0.9005, "T_J": 2.0259 }, "closure_15pct": { "S_S0": 0.8521, "T_J": 1.4532 }, "closure_20pct": { "S_S0": 0.8016, "T_J": 1.1018 }, "closure_25pct": { "S_S0": 0.7485, "T_J": 0.8588 }, "closure_5pct": { "S_S0": 0.9501, "T_J": 3.3346 } }, "entropy_limit": 4.3944 } }